Does wedding ring goes on the left ring finger, because it's the only finger with a vein that connects to the heart?

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No, Its not true

Biologically its not only vein that goes to heart, on this we found on wikipedia:

Before medical science discovered how the circulatory system functioned, people believed that a vein of blood ran directly from the third finger on the left hand to the heart. Because of the hand-heart connection, they chose the descriptive name vena amori, Latin for the vein of love, for this particular vein.

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